Chlorinated polyvinyl chloride (CPVC) is an important engineering thermoplastic due to its:
- Relatively low cost
- High glass transition temperature
- High heat distortion temperature
- Chemical inertness
- Outstanding mechanical, dielectric, and flame and smoke properties
CPVC was first commercialized by Lubrizol in the early 1960s and has since proven its value in a variety of industrial applications where high use temperature and corrosion resistance are desirable.
Today, Lubrizol's CPVC material is sold under three brand names: Corzan® Industrial Systems (industrial applications), BlazeMaster® (fire sprinkler systems) and FlowGuard Gold® (residential and commercial plumbing).
What is CPVC?
Conceptually, CPVC is a PVC homopolymer that has been subjected to a chlorination reaction. Typically, chlorine and PVC react according to a basic free radical mechanism, which can be brought about by various approaches using thermal and/or UV energy.
What Is the Difference Between CPVC and PVC?
In PVC, a chlorine atom occupies 25 percent of the bonding sites on the carbon backbone, and the remaining sites are filled by hydrogen.
CPVC differs from PVC in that approximately 40 percent of the bonding sites on the backbone are filled with chlorine atoms. The chlorine atoms surrounding the carbon backbone of CPVC are large atoms that protect the chain from attack.
The chlorine content of base PVC can be increased from 56.7 percent to as high as 74 percent, though typically most commercial CPVC resins contain 63 to 69 percent chlorine.
Diagram of CPVC (left) at a molecular level compared to PVC (right). The red spheres represent chlorine elements.
Increased Temperature Resistance
As the chlorine content in CPVC is increased, the glass transition temperature (Tg)—temperature region where the polymer transitions from hard, glassy material to a soft, rubbery material—increases significantly.
It’s the additional chlorine molecules that protect the polymer’s carbon backbone, which in turn protects its structural integrity against heat.
The increased heat resistance allows CPVC to perform at higher operating pressures.
CPVC resin is then infused with additives to enhance many of the CPVC resin’s inherent properties, while easing its processability.
It’s this process that really starts to set CPVC apart from other thermoplastic and metal piping systems, and fortifies it against the demanding environments of industrial plants.
Basic Physical Properties of CPVC
CPVC is inherently inert to acids, bases, salts and aliphatic hydrocarbons, all of which tend to eat away at metals. It's this inherent chemical resistance, coupled with its temperature and pressure resistance, that enable its use in a variety of industrial and commercial applications.
Other key properties of Corzan® CPVC are listed in the table below. You can also see more details in the piping specification and ducting specification sections.
CPVC Product Types
CPVC is a flexible, versatile compound that can be manufactured or fabricated into a number of product forms or geometries using standard molding techniques, primarily extrusion and injection molding.
- Pipe and Fittings: The corrosion and temperature resistance remain, while pressure ratings required of an application can vary with schedule, pipe size, compound type and temperature.
- Ducting: With increasing air emission regulations, the need for reliable fume handling systems, especially in corrosive environments, is growing rapidly. CPVC is available in round duct, fabricated duct fittings, industrial sheet, and welding rod. These components can be designed and fabricated into entire fume handling systems.
- Sheet and Lining: The excellent corrosion resistance and fire performance of CPVC can be applied to various industrial applications and be overwrapped with Fiber Reinforced Polyester (FRP).
Common Applications of CPVC
The inherent chemical resistance of CPVC, coupled with its temperature and pressure resistance, enable its use in a variety of industrial and commercial applications.
CPVC is commonly specified in applications ranging from chemical processing plants and mineral processing plants to residential homes and hotel plumbing.
CPVC is a problem-free, long-lasting solution for the harshest industrial environments, and is often specified in the following industries:
- Chemical Processing: Reliably transport aggressive chemicals at high temperatures, under pressure, without corrosion concerns.
- Chlor Alkali: Transport chemicals through some of the most corrosive environments imaginable without corrosion concerns.
- Commercial Plumbing: Eliminate corrosion, reduce maintenance costs and improve overall reliability.
- Mineral Processing: Withstand the demands of precious and raw material processing operations.
- Power Generation: Stand up long term to the high pressures and corrosive chemicals commonly used by power plants.
- Semiconductor: Meet the high purity standards for cleanrooms and eliminate corrosion concerns caused by aggressive chemicals.
- Wastewater Treatment: Put an end to corrosion, even when transporting the most aggressive disinfection chemicals.
Residential and Commercial Fire Sprinklers
Whether a single home or a demanding high-rise, CPVC offers competitive flame and smoke properties and a simpler joining method than many alternatives. Use cases include:
- Single family (NFPA 13D): Standalone housing, mobile homes.
- Residential (NFPA 13R): Structures of four stories and less, including condos, hotels or motels, and multi-unit apartment buildings.
- Commercial Residential (NFPA 13): Structures of five stories and more, including high-rises, condos, hotels, and multi-unit buildings.
CPVC Installation Joining Methods
The recommended joining method for CPVC installation will depend on the product type, but across-the-board, CPVC offers the following installation advantages:
- Lightweight: CPVC is approximately 1/8th the weight of comparably sized steel, which helps to reduce worker strain and injuries, and eliminates the need for heavy equipment.
- Easy to cut: Compound properties make CPVC easier to cut than metals, allowing for more efficient on-site fabrication.
- Simple to install and maintain: CPVC installation requires no complex tools, electricity or highly skilled (and expensive) labor.
- Safer: No open flame or ignition sources are required to join the material.
There are a variety of seam welding options designed to effectively seal components together while maintaining the structural integrity of the material. Recommended installation methods will vary by product type:
- Pipe and fittings: Solvent cementing, hot-air welding, hot-plate welding, threading, and flanging.
- Ducting: Solvent cementing, hot air welding, thermoforming, extrusion welding and hot-plate welding.
- Sheet and Lining: High speed hot air welding and hot plate butt welding.
Why Not All CPVC Is the Same
Although CPVC as an industrial piping material has a long, proven history, not all CPVC systems perform equally. While some bottom-line benefits of CPVC are common regardless of manufacturer, CPVC compounds are often differentiated by the level of performance they provide.
In the same way that two different types of industrial metallic pipe will likely perform differently, it is safe to assume that two CPVC industrial pipes made from different compounds will yield different results.
Corzan Industrial Systems and our manufacturers, for example, have undergone different types of tests regarding:
- Minimum burst pressure requirements
- Dimensional tolerances
- Residual stress requirements
- Drop impact requirements
- Fusion property testing
You shouldn't assume that the test results from one CPVC compound will parallel the results for a different compound.
Where to Buy Corzan® CPVC
Corzan Industrial Systems only partners with manufacturers that have a proven track record of quality and reliability. These manufacturers are carefully chosen to convert Corzan CPVC into the high performance piping systems, ducting, sheets and lining our customers rely on.
Learn more about our partner manufacturers.